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Mineral Elements and Greenhouse Crop Fertilization
Plants are approximately 90% water. The remaining dry matter
is composed of the elements listed below. The elements C, H and
O comprise 89% of the dry matter of most plants. The plant is able
to derive these 3 elements from water and the atmosphere. The other
elements constitute only about 1% of the total plant weight and
about 11% of the dry matter. However, these are the elements that
need to supplied in the fertilization program.
|
Element |
Percent (%)of dry matter |
| Carbon |
89.0 |
| Hydrogen |
| Oxygen |
| Nitrogen |
4.0 |
| Phosphorus |
0.5 |
| Potassium |
4.0 |
| Calcium |
1.0 |
| Magnesium |
0.5 |
| Sulfur |
0.5 |
| Iron |
0.02 |
| Manganese |
0.02 |
| Zinc |
0.003 |
| Copper |
0.001 |
| Boron |
0.006 |
| Molybdenum |
0.0002 |
| Chloride |
0.1 |
| Nickel |
0.0005 |
These elements can be broken into 3 major categories.
The first are referred to as primary macroelements because the plant
needs relatively large amounts of these elements. The primary macroelements
include nitrogen, phosphorus, and potassium. The second category
is the secondary macroelements and includes calcium, magnesium and
sulfur. The third category is the microelements. These are required
in smaller amounts but are no less important than the primary and
secondary macroelements. The microelements include iron, manganese,
zinc, copper, boron, molybdenum, chloride, and nickel.
Primary Macroelements
The primary macroelements nitrogen (N), phosphorus (P) and potassium
(K) are required in the highest amounts; These are the three elements commonly listed on a fertilizer
label (see Reading and Understand Fertilizer Labels below).
Individual fertilizer salts (i.e. ammonium nitrate, calcium nitrate,
potassium nitrate, ammonium phosphate, potassium sulfate, etc.)
may be used to provide these mineral elements to a crop. These three
elements may also be provided using a commercially prepared complete
fertilizer (i.e. 20-10-20) in a liquid or slow-release form.
Nitrogen is required in the highest amount of all of the mineral
elements. Nitrogen is often used as the benchmark or starting point
for determining the fertilizer solution concentration when conducting
a liquid fertilization program. For example, a solution containing
250 parts-per-million (ppm) N may be prepared. In this case, it
is assumed that enough P and K are being provided to obtain the
proper ratio of N:P and N:K. Generally, N and K should be provided
in nearly equal amounts (although in reality K is often supplied at levels
somewhat lower than N). The P level should be approximately 15%
- 30% of that of the N. Where a constant liquid fertilization program
is being used, a N concentration of 150 - 300 ppm is common for
most greenhouse crops (except with no-leach systems where lower
concentrations are used). Some common sources of N include ammonium
nitrate, urea, ammonium phosphate, calcium nitrate ,
and potassium nitrate .
Plants may take up N either as nitrate (NO3-)
or ammonium (NH4+). However, the ratio of
these two forms is important. Not only must the amount of N being
supplied be considered, but also the form in which it is supplied.
For most greenhouse crops, never more than 50% (and usually not
more than about 25%) of the N should be supplied as NH4+.
However, the optimal NH4+:NO3-
ratio depends upon plant species and time of year.
Both NO3- and NH4+
are commonly used as N sources for greenhouse crops. Although NH4+
may be taken up directly by the plant, it is also converted to NO3-
in the soil by microorganisms.
2(NH4+) + 3(O2) => 2(NO2=)
+ 2(H2O) + 4(H+)
(NO2=) + (O2) => 2(NO3-)
The production of protons in the first step of this conversion
is one reason why NH4+-based fertilizers are
acidic and tend to cause the pH of the substrate to go down over
time. Ammonium nitrogen is preferred where it can be used because
it is relatively inexpensive. However, high levels of ammonium can
be toxic to plants. Levels can build up over time due to over application
of ammonium or due to low substrate temperatures in winter months
since conversion of ammonium to nitrate is slowed under low temperatures.
This is why many growers (particularly in northern climates) use more ammonium-based nitrogen during warm
months but cut back and shift to nitrate-based nitrogen during winter
months. Urea must first be converted to NH4+
before the plant can take it up. Under low temperatures conversion
of urea can also be slowed and toxic levels may build up.
Calcium [Ca(NO3)2] and potassium nitrate
(KNO3) are common nitrate-nitrogen sources. They are
more expensive than urea and ammonium nitrate. These fertilizers
are often referred to as basic or alkaline fertilizers since their
use tends to cause the substrate pH to increase over time. This
occurs because the root excretes an OH- for each NO3-
that it absorbs. The release of OH- (hydroxyl ions) into the
the substrate solution causes the pH to increase.
Phosphorus is sometimes supplied by incorporating superphosphate(0-20-0)
or triple superphosphate (0-45-0) into the substrate. Depending
upon the crop and the rate of incorporation, this may supply the
entire phosphorus need of the crop. Phosphorus may also be supplied
through the fertilization program. Most commercial fertilizers,
whether slow-release or liquid, supply phosphorus using ammonium
phosphate or diammonium phosphate. Although the recommended range for
substrate P levels is very wide, high P levels can promote elongation
in seedings. Since excessive elongation is undesirable, excessive P
fertilization should be avoided.
Potassium is supplied through the fertilization program. Most commercial
fertilizers (water soluble and slow release) supply potassium from potassium nitrate.
Potassium nitrate may also be used as a potassium source when preparing a custom-designed
fertilizer solution.
Secondary Macroelements
The secondary macroelements calcium (Ca), magnesium (Mg) and sulfur
(S) are required in lower amounts than the primary microelements
but higher amounts than the microelements. They are provided to
a crop by incorporation into the substrate or through the fertilization
program.
Calcium is at least partly supplied by using some type of
limestone in the substrate (such as is added to adjust pH). This
can often supply the entire Ca requirement if the crop time is not
too long. However, long-term crops or crops that require higher
levels of Ca (i.e. poinsettia) may need additional applications
during the production cycle. Calcium may be applied during production
by including Ca(NO3)2 in the fertilizer solution
or by using a commercial fertilizer that contains Ca (i.e. Excel
15-5-15 Ca-Mg). Calcium may also be applied as a foliar spray using
calcium nitrate, calcium chloride or a commercially available chelated
calcium such as T.H.I.S. or dynocal.
Calcium Sulfate (gypsum) may be added to the substrate in lieu of
limestone when a source of calcium is desired but not a significant
pH increase.
If dolomitic limestone is used to adjust the substrate pH, all
or part of the Mg requirement of the plant may be met. However,
especially for long-term crops or crops that require high levels
of Mg, additional Mg may be needed during production. Although many
commercial fertilizers now include Mg, magnesium sulfate (Epsom
salts) is commonly used to supplement the Mg supplied to the plant.
Magnesium sulfate is usually applied at a rate of 8-16 oz per 100
gallons of water (226 - 452 grams / 379 liters). At this rate, magnesium
sulfate is applied approximately every 6 - 8 weeks depending upon
the crop and growing conditions. Some producers apply low levels
of Mg continuously in the fertilization program.
Sulfur may be supplied in several ways. Mineral soils contain
S, and if a significant amount of mineral soil is included in the
substrate, the crop's S requirement may be met. Elemental sulfur,
aluminum sulfate and iron sulfate serve as sources of S. Elemental
sulfur reacts and releases S slowly into the substrate solution
whereas aluminum sulfate and iron sulfate react quickly in the substrate.
These three materials will also cause the pH of the substrate
to decrease if used in large enough concentrations. Many commercial fertilizers
also contain S, since sulfate salts (i.e. iron sulfate, zinc sulfate) are
often (but not always) used to supply microelements.
Microelements
The microelements iron (Fe), manganese (Mn), zinc (Zn), copper
(Cu), boron (B), molybdenum (Mo), chloride (Cl-) and
nickel (Ni) are required by plants in only very small amounts. However,
they are just as important as the macroelements. Microelements serve
as enzyme cofactors or as part of photoreceptors.
When field soil is used in the substrate, some or the entire microelement
requirement may be met by the elements provided by the mineral constituents
of the field soil. However, many producers still supplement the
substrate with additional microelements to insure an adequate supply.
In substrates without soil, nearly all of the microelements must
be supplied through the fertilization program.
There are several methods used to provide microelements. A microelement
fertilizer package (i.e. Promax, Esmigran, Micromax or other fritted
trace element packages) may be incorporated into the substrate,
or plants may be "watered in" with a water-soluble microelement
(i.e. S.T.E.M.) solution soon after planting. Micronutrients may
be included in the liquid fertilization program or may be included
in the slow-release fertilizer used. The required amount may be
applied as a single application or as several applications during
the crop cycle. Caution must be taken not to apply an excess of
micronutrients since toxicities can occur particularly under low pH
(i.e Fe-Mn toxicity in marigold).
There are different types of complete microelement packages available
and they are designed for different purposes. Some are water-soluble
(i.e. S.T.E.M.) and are designed to be applied as a liquid drench
or to be included in the liquid fertilization program. The microelements
in these fertilizers are typically supplied as sulfur salts (i.e.
iron sulfate, manganese sulfate, zinc sulfate, etc.). Others are
designed to be incorporated into the substrate. These may be granular
salts or oxide forms (i.e. zinc oxide, manganese oxide, etc.) of
the minerals. Microelements may also be incorporated into glass
or clay particles (fritted). This allows for easier mixing and results
in a slower release of the microelements into the substrate solution.
Some crops require additional levels of certain micronutrients
beyond what is typically supplied by complete microelement fertilizers.
Most commonly, plants may require additional Fe (i.e. blueberry),
Mo, (i.e. poinsettia), or B (i.e. celery). Iron may be supplied
using a chelated iron compound such as Sequestrene 330 or iron sulfate.
Molybdenum may be supplied using ammonium molybdate or sodium molybdate.
Boron may be supplied through borax, ammonium borate or sodium borate.
Slow-Release and Water-Soluble Fertilizers
Mineral elements may be supplied through a liquid fertilization
program or a slow-release fertilizer. Liquid fertilization is most
common with greenhouse crops.
Slow-release fertilizers are marketed under several brand names
(i.e. Osmocote, Nutricote, Sierra) and are available in numerous
formulations. Slow-release fertilizers are produced by encapsulating
water-soluble fertilizer elements in a polymer that allows water
to enter, and the elements to slowly diffuse out into the surrounding
substrate solution. The polymer may be altered to allow a slower
or more rapid release of the fertilizer elements. Therefore, slow-release
fertilizers will also indicate the release period (i.e. 60-day,
100-day etc.) in addition to the guaranteed analysis (i.e. 20-10-20)
and the recommended application rate for various crops and container
sizes.
Slow-release fertilizers may be top-dressed onto the surface of
the substrate or incorporated into the substrate. When using subirrigation
systems, the slow-release fertilizer must be incorporated into the
substrate.
In some cases, a grower might incorporate a slow-release fertilizer
into the substrate at half the recommended rate and supply the remaining
fertility requirement through a liquid fertilization program. This
provides increased flexibility since once a slow-release fertilizer
is incorporated into a substrate it can't be removed and excess
nutrients can't be leached out.
Water-soluble fertilizers
are designed to be injected into irrigation
lines. Water-soluble fertilizers are marketed under different brand
names and are available in numerous formulations (i.e. 20-10-20,
15-5-15, etc.). Many commercially prepared water-soluble fertilizers
may contain a dye that allows visual verification that fertilizer
is being injected into the fertilization line. Some greenhouse operations
may prepare their own water-soluble fertilizers using individual
mineral salts [i.e Ca(NO3)2, KNO3].
Liquid fertilization may be conducted as once per week applications
or as frequently as with each irrigation. However, rates must be
adjusted accordingly.
Reading and Understanding Fertilizer Labels
Fertilizer labels contain a great deal of valuable information.
In order to prepare fertilizer solutions, properly apply a fertilizer,
or to effectively use a fertilizer, the information on the label
needs to be understood.
A fertilizer label lists the % by weight of N ,
P2O5
and K2O.
Therefore, a 20-20-20 is 20% N, 20% P2O5
and 20% K2O. A 100 lb bag would contain 20 lbs N, 20
lbs P2O5 and 20 lbs K2O. However,
this does not tell us how much actual N, P and K are in 100 lbs
of 20-20-20. To determine this we need to know that P2O5
is 43% P and K2O is 83% K (determined from molecular
weights). Therefore, a 20-20-20 contains:
0.20 N x 100 lbs = 20 lbs N
(0.20 P2O5 x 0.43) x 100 lbs = 8.6 lbs
P
(0.20 K2O x 0.83) x 100 lbs = 16.6 lbs K
Therefore, a 20-20-20 is actually 20% N - 8.6% P - 16.6% K. All
of these calculations are based on molecular/atomic weights, so
if you know the atomic weights you can determine the actual amount
of any element from any fertilizer or fertilizer compound. For example,
100 lbs of Epsom salts (MgSO4 - 7 H2O) will
contain: 24 + 32 + 4(16) +7(18) = 246 and (24/246) x 100 = 9.8 lbs
of Mg.
This is not the only important information on a fertilizer label.
Fertilizer labels contain a great deal of potentially important
information. Fertilizer labels provide information regarding the
actual components used to formulate
the fertilizer, the ratio of
NH4+ to NO3-,
whether
the fertilizer is acidic or basic , the
electrical conductivity of
different concentrations of the fertilizer, and application recommendations.
The links below connect to sample fertilizer labels.
| 
13-0-44
|

15-0-15
|

15-5-15
|

16-4-12
|

Compound 111
|
| 
21-5-20
|

20-5-19
|

S.T.E.M.
|

Osmocote
|

Osmocote Plus
|
Fertilizer Calculations
Many commercial fertilizers will provide application
rates on the label (especially slow-release fertilizers). However,
in some cases the application rate may need to be adjusted or individual
mineral salts may be used to prepare a custom fertilization program.
In either case, it is important to understand how to calculate fertilizer
concentrations. These calculations need only be performed for a
liquid fertilization program. Dry fertilizers or slow-release fertilizers
are applied at recommended rates per container or cubic yard (as
recommended on the labels).
Before working through a few examples, it is important to understand
the term parts-per-million (ppm). When mixing two liquids of the
same density and containing 100% of the material of interest (pure),
a ppm is simply 1 part (active ingredient of the material of interest)
to 999,999 parts water. However, the materials used are usually
not pure, and the solutions containing the active ingredients have
densities different from that of water. Additionally, with fertilizers,
solids are usually being added to water. In these cases the calculations
are based on weight of active ingredient where 1 unit of weight
of the material of interest to 999,999 weight units of water.
One ml of water weighs 1 gram at 20° C. Therefore, 1 liter of water
weighs 1000 grams or 1,000,000 mg. This gives us the standard definition
of a ppm as:
1 ppm = 1 mg.L-1
It is also helpful to remember that 1% = 10,000 ppm (100 x 10,000
= 1,000,000). Therefore, a 1% solution is equivalent to 10,000 ppm.
Also remember that these calculations are based on the amount of
active ingredient or element of interest not the carrier material.
1. Determine how many mg.L-1 of a 20-20-20
are required to produce a 100-ppm N solution.
100 ppm = 100 mg.L-1
If we were dealing with pure N, we would add 100 mg.L-1.
However, the material is only 20% N.
Therefore, 100 mg / 0.20 = 500 mg
500 mg 20-20-20 per liter provide 100 mg.L-1
(or ppm) N.
2. Determine how many mg.L-1 of a 20-20-20
are required to produce a 100 ppm K solution.
100 ppm = 100 mg.L-1
If we were dealing with pure K, we would add 100 mg.L-1.
However, the material is 20% K2O, and K2O
is only 83% K.
To determine the % K in this fertilizer, we have 0.20 x 0.83
= 0.166 or 16.6% K
Therefore, 100 mg / 0.166 = 602 mg
602 mg 20-20-20 per liter provide 100 mg.L-1
(or ppm) K.
3. In example 1 we determined that 500 mg.L-1
of 20-20-20 provided 100 ppm N. How much P is provided by this solution?
P2O5 is 43% P
Therefore, 0.20 x 0.43 = 0.086 or 8.6% P
500 mg x 0.086 = 43 mg
43 mg P/L = 43 ppm P
4. How many mg of 20-20-20 need to be used in a liter of stock
solution that when put through a 1:100 injector will provide 100
ppm N?
From example #1, we know that 500 mg 20-20-20/l = 100 ppm N.
1 liter of stock will result in 101 liters of total solution
when put through the injector. Therefore, 500 mg.L-1
x 101 L = 50,500 mg (50.5 g) in L liter of stock.
5. How many mg.L-1 of Ca(NO3)2
and KNO3 are required to produce a 100 ppm N solution
that provides 75% of the N from Ca(NO3)2 and
25% of the N from KNO3. Assume that both fertilizers
are pure.
40 + [14 + (16)3]2 = 164 28/164 = 0.17 or 17%
39 + [14 + (16)3] = 101 14/101 = 0.14 or 14%
Ca(NO3)2 = 17% N
KNO3 = 14% N
Need 100 mg.L-1
Thus we need 0.75 x 100 = 75 mg from Ca(NO3)2
and 0.25 x 100 mg = 25 mg from KNO3.
75 mg / 0.17 = 441 mg Ca(NO3)2
25 mg / 0.14 = 179 mg KNO3
Nutritional Monitoring and Management
Fertility management is one on of the most challenging aspects
of greenhouse crop production. Many factors impact the nutritional
status of a crop and should be considered as when developing a fertilization
program, monitoring the mineral nutrition status of a crop and making
adjustments to the fertilization program.
Crop Stage
Newly planted cuttings, young seedlings and plugs require a lower
mineral nutrition level than actively growing crops. Typically,
younger plant materials are grown at lower fertility levels and
as the root system develops and the plants start to grow rapidly,
fertility is increased.
Time of Year
Under warm temperatures and high light levels, plants grow more
rapidly and utilize mineral nutrients at a faster rate. As temperatures
and light increase, fertility level may need to be increased to meet the
crop's increased demand. Under the cooler temperatures and lower
light conditions of winter months, fertilization may need to be
reduced.
Ammonium is converted to nitrate in the substrate by microorganisms.
When soil temperatures are low, microorganisms are less active
and the conversion of ammonium to nitrate is slower. Under these
conditions, ammonium can build up to toxic levels unless the amount
of ammonium supplied to the crop is reduced. Therefore, growers
often change the form of nitrogen supplied to the crop during
late fall, winter and early spring. During these times, growers
may shift from using nitrogen sources with high levels of ammonium
to those with little or no ammonium to prevent the build up of
ammonium in the substrate.
Amount of Element
Mineral nutrients may be present at concentrations that are deficient
(below the level the plant could utilize), concentrations that
are in excess (above the level the plant could utilize), concentrations
that are phytotoxic (concentrations at which some type of physiological
damage is done to the plant) or at concentrations that interfere
with the uptake of other mineral elements (high NH4+
can inhibit the uptake of Ca++). The objective in a
fertilization program is to maintain each element within an optimal
range throughout the crop cycle.
When using a granular fertilizer material such a superphosphate
to supply phosphorus or dolomitic limestone to provide calcium
and magnesium, the fertilizer material slowly breaks down or dissociates
in the substrate and releases the desired mineral element over
time. However, very early in the crop cycle, the desired mineral
nutrient may be below the optimal level until enough is released
into the substrate solution to increase the level of the mineral
element into the optimal range. The level of the desired mineral
element may then be within the optimal range for many weeks. However,
over time, the level may drop and fall to concentrations below
optimal especially for long-term crops. Fertilizer salts that
are readily soluble (i.e. calcium nitrate, potassium nitrate,
magnesium sulfate) result in a more rapid increase in the level
of the mineral elements they supply, but the level may also drop
more quickly unless additional sources are provided.
Slow-release fertilizers are designed to allow the fertilizer
salts held within the polymer coating to slowly dissolve and leach
into the substrate. This allows for a more constant supply of
the mineral elements and allows them to be maintained within an
optimal range over a specified period of time. However, even with
the use of slow release fertilizers, there is a
period of time required for the fertilizer salts to leach
into the substrate and increase the levels of mineral elements
to the optimal ranges. Additionally, over time the level of salts
leaching from the slow release fertilizer will drop and the level
of mineral elements in the substrate may drop below optimal levels.
When using liquid fertilization, periodic applications of fertilizer
(typically 300 - 500 ppm N) are made through the irrigation system.
After fertilization, the level of the applied mineral nutrients
increase rapidly
and may even reach levels that are above optimal depending upon
fertilizer concentration. In between fertilization cycles, the
level of mineral nutrients decreases as the plants take them up.
Between fertilizations, the level might stay within the optimal
range or might drop below optimal levels depending upon the concentration
of the fertilizer solution used, the time interval between fertilizations
and the rate of crop growth.
Constant liquid fertilization is one in which the concentration
of the fertilizer solution is reduced (i.e. 150 - 250 ppm N) but
is applied with each irrigation. Constant liquid fertilization
allows for a more
constant fertility level to be maintained.
Proportions/Ratios of Elements
Not only are the absolute amounts of mineral elements provided important,
but the ratios of the mineral elements to one another are important.
As a general rule, N and K should be provided in near equivalent
amounts and P should be provided at 15% - 30% the rate of N. There
are exceptions to this rule since some crops require higher or
lower N:K ratios. For example carnation grows and develops best
when provided K at 1.5 times the amount of N and cyclamen grows
and develops best when provided K at twice the concentration of
N. Most foliage plants develop best when provided 1.5 times as
much N as K. Typically Mg is provided at 50% of the rate as Ca.
Microelements are provided at much lower concentrations than the
primary and secondary macroelements.
Problems can occur if mineral nutrients are out of balance. Excess
P (in relation to N and K) can cause elongation of annual bedding
plant species. Excess levels of certain elements can cause deficiencies
of other mineral elements because of competitive uptake. For example,
excess K can cause N deficiency and high levels of NH4+
can cause Ca deficiency.
Form of Element
The form in which an element is provided can have a significant
impact on plant growth. Plants may take up nitrogen as either
ammonium or nitrate. Plants however respond differently to the
two forms of nitrogen. While some plants thrive when provided
nitrogen from sources high in ammonium (i.e. azalea). Other species
perform better when most nitrogen is provided as nitrate with
only a small proportion of the total nitrogen coming from ammonium.
Ammonium can either be toxic at certain levels or may inhibit
the uptake of calcium and thus induce calcium deficiency symptoms.
Substrate Components
The substrate components may contain mineral elements and at
least partially provide for the crops requirements. Vermiculite
contains significant amounts of potassium and although it cannot
meet the entire crop need, it can contribute towards the crop's
potassium requirement. Composted manures contain significant levels
of micronutrients and if composted manures are added to the substrate
they may provide enough micronutrients to meet the crops need.
In some cases, a substrate component may contain toxic levels
of one or more mineral elements that limit its use (i.e. shredded
rubber tire contain toxic levels of zinc).
Substrate pH
The pH
of the substrate affects the availability of mineral elements.
Under low pH, microelements such as Fe, Cu, and Zn become more
available. Under high pH, even if these elements are present in
the substrate, they may be unavailable for uptake by the plant
and therefore the plant may suffer from pH-induced deficiency.
Under high pH, elements such as Ca, Mg and Mo become more available. Under
low pH, even if these elements are present in the substrate, they
may be unavailable for uptake by the plant.
The fertilization program may in turn be designed to manipulate
substrate pH. Different fertilizers can have different effects
on substrate pH. Ammonium nitrogen causes a reduction in the substrate
pH and nitrate nitrogen causes an increase in substrate pH. Fertilizer
salts such as NH4NO3 will tend to cause
the pH to decrease. Calcium nitrate [Ca(NO3)2]
and KNO3 will tend to cause the pH to increase. Premixed
fertilizers are composed of various fertilizer salts and may have
different effects on substrate pH depending upon the fertilizer
salts used to formulate the fertilizer. Therefore, by selecting
fertilizers based upon their effect on substrate pH, the pH of
the substrate may be at least partially manipulated.
|
Potential Acidity and Basicity of Select
Fertilizer Salts and Commercial Fertilizers |
|
Fertilizer |
Potential
Acidityz |
Potential
Basicityy |
| Ammonium sulfate |
2,200 |
|
| Urea |
1,680 |
|
| Diammonium phosphate |
1,400 |
|
| Ammonium nitrate |
1,220 |
|
| Diammonium phosphate |
1,120 |
|
| Calcium nitrate |
|
400 |
| Potassium nitrate |
|
520 |
| Sodium nitrate |
|
580 |
| 15-5-15 Cal-Mag |
|
135 |
| 21-5-20 |
418 |
|
| 20-10-20 |
393 |
|
| 20-20-20 |
610 |
|
| 15-0-15 |
319 |
|
| 16-17-17 |
440 |
|
z Pounds of calcium carbonate required to neutralize
the acidity of one ton of the listed fertilizer. |
y One ton of the specified fertilizer has the
acid-neutralizing effect of the specified number of pounds
of calcium carbonate. |
Substrate Cation-Exchange-Capacity
The higher the cation-exchange capacity (C.E.C.) of the substrate,
the greater the substrate's ability to retain cations. Since many
of the mineral elements are cations, the greater the C.E.C., the
greater the substrate's nutrient holding capacity. Mineral elements
held by the substrate can be exchanged with substrate solution
and be available for uptake by the plant. In most greenhouse situations,
all of the macroelements and microelements are provided as a continuous
liquid feed so the C.E.C. is of less importance because mineral
elements are supplied with each irrigation and don't need to be
retained for future uptake by the plant. The C.E.C. can be important
in constant liquid feed where microelements are only supplied
at the being of the crop production or only periodically since
the mineral element cations need to be retained in the substrate
rather than being leached out.
Cation-exchange capacity also impacts mineral nutrition through
its role in substrate pH. The higher the C.E.C., the more resistant
the substrate is to changes in pH. As previously discussed, pH
impacts nutrient availability. A substrate with a high C.E.C.
will be less subject to pH changes and thus changes in mineral
element availability.
Substrate Electrical Conductivity
Electrical conductivity (E.C.) provides an overall measure of
the mineral elements in the substrate solution. However, it does
not provide a measure of the concentration of any specific mineral
element. If a complete liquid fertilization program is being conducting
in which all macroelements and microelements are being provided
in the appropriate proportions, E.C. can provide a good indication
as to whether the overall fertility program is within an acceptable
range. The acceptable range for E.C. varies with crop and crop
stage (just as does fertility level). However, typically an E.C.
of 2.0 - 3.0 mmho/cm is desirable for most actively growing crops.
Lower E.C. levels are desirable for seedlings and plugs and higher
E.C. levels may be desired for crops requiring high fertility
levels. Electrical conductivities significantly below desired
levels might be an indicator that the fertility level is below
optimal and the fertilizer concentration being applied needs to
be increased (or the frequency of fertilization increased). Electrical
conductivities significantly above the desired level may be an
indicator that fertility levels are too high in general or that
one or more mineral elements are too high. If the E.C. is too
high, a reduction in fertilization might be required, or if the
E.C. is very high, clear-water leaching may be required.
Electrical conductivity can also be used to monitor the
fertilizer solution being applied to a crop. A given concentration
of a fertilizer (or fertilizer salt) will always have a specific
E.C. This information is printed on most fertilizer labels. A
sample of the fertilizer solution can be collected as it comes
out of the hose, drip tube or emitter. The E.C. of the fertilizer-containing
sample is determined. An E.C. of the water source is determined
(without fertilizer). The E.C. of the water without fertilizer
is subtracted from the E.C. of the fertilizer-containing solution.
The resulting E.C. should be similar to the expected E.C. for
the concentration of the fertilizer being used. If the E.C. is
not correct, either the amount of fertilizer used was incorrect
or the injector was not working correctly.
Water Quality
Water quality impacts the nutritional program in two primary
ways. First, the water may contain minerals (i.e. calcium carbonates,
borates, iron, sulfur, etc.) that may provide a portion of the
nutritional requirement of the crop. Water quality can also impact
the pH of the substrate (see water quality under Irrigation
learning unit). Through this mechanism, the water can affect the
availability of mineral elements for uptake by the plant. For
example, if a very alkaline water source is used (and no corrective
measures are taken), the pH of the substrate will increase over
time. As the pH of the substrate increases and becomes alkaline,
many of the microelements (i.e. Fe, Cu, Zn, etc.) become less
available. As the pH continues to increase over time, microelements
may become increasingly unavailable, and a pH-induced microelement
deficiency may occur.
Irrigation Method
Irrigation method affects fertility primarily by affecting the
degree of leaching of mineral elements from the substrate. When
overhead irrigating, the water flows through the substrate and
drains from the container. As the water drains from the container,
mineral elements are leached from the substrate. If overhead irrigation
is used and conducted in such a way as to minimize leaching, less
loss of mineral elements from leaching occurs. If subirrigation
is used, leaching, and thus loss of mineral elements does not
occur. Most fertility recommendations have been developed assuming
overhead irrigation with leaching is to be used. If subirrigation
without leaching is conducted, fertilization levels are often
reduced by 30% to 50%.
Interpreting Substrate and Tissue Tests
It is important to understand how to use information from substrate
and tissue tests to adjust the fertilization program. Acceptable
ranges for substrate tests using a saturated media extract (SME)
are listed in the table below. On-site pH and electrical conductivity
measurements should be conducted regularly to monitor changes in
pH and E.C. over time. Properly monitoring the fertility status
of a crop can allow for corrections of potential problems before
there is significant damage or crop loss and when corrections are
more easily made.
| Recommended
Ranges For Mineral Elements For Most Ornamental Greenhouse
Cropsz |
| pH |
5.5 - 6.5 |
| E.C. (mmho/cm) |
0.75 - 3.5 |
| NO3-
(ppm) |
40 - 200 |
| NH4+
(ppm) |
0 - 40 |
| P (ppm) |
5 - 60 |
| K (ppm) |
40 - 360 |
| Ca (ppm) |
50 - 250 |
| Mg (ppm) |
25 - 125 |
| S (ppm) |
50 - 250 |
| Fe (ppm) |
0.3 - 3.5 |
| Mn (ppm) |
0.3 - 3.5 |
| Zn (ppm) |
0.3 - 3.5 |
| Cu (ppm) |
0.001 - 0.6 |
| B (ppm) |
0.06 - 0.6 |
| Mo (ppm) |
0.2 - 0.15 |
| Cl (ppm) |
not established |
z Based on a saturated media paste extract (SME).
Low end is usually recommended for seedlings and young transplants
with medium and high values being more suitable for established
actively growing plants. |
Recommended tissue levels of mineral nutrients for some common
greenhouse crops are listed below. These are levels for dried and
ashed fully expanded leaves. Tissue tests are sometimes required
to specifically diagnose a mineral element deficiency.
| Recommended
Nutrient Levels In Leaf Tissue of Some Common Greenhouse
Cropsz |
| |
Poinsettia |
Chrysanthemum |
Seed geranium |
Impatiens |
Easter lily |
| Nitrogen (%) |
4.0 - 6.0 |
4.0 - 6.0 |
3.7 - 4.8 |
4.3 - 5.3 |
2.4 - 4.0 |
| Phosphorus (%) |
0.2 - 1.0 |
0.2 - 1.2 |
0.3 - 0.6 |
0.6 - 0.8 |
0.1 - 0.7 |
| Potassium (%) |
1.5 - 5.0 |
1.0 - 10.0 |
3.3 - 3.9 |
1.8 - 2.8 |
2.0 - 5.0 |
| Calcium (%) |
0.4 - 2.0 |
0.5 - 4.6 |
1.2 - 2.1 |
2.9 - 3.3 |
0.2 - 4.0 |
| Magnesium (%) |
0.2 - 1.0 |
0.1 - 1.5 |
0.2 - 0.4 |
0.6 - 0.8 |
0.3 - 2.0 |
| Iron (ppm) |
100 - 300 |
20 - 750 |
120 - 340 |
405 - 685 |
100 - 250 |
| Manganese (ppm) |
45 - 300 |
25 - 375 |
110 - 285 |
205 - 490 |
50 - 250 |
| Zinc (ppm) |
25 - 150 |
5 - 35 |
35 - 60 |
65 - 70 |
30 - 70 |
| Copper (ppm) |
5 - 15 |
5 - 50 |
5 - 15 |
10 - 15 |
5 - 25 |
| Boron (ppm) |
20 - 200 |
20 - 200 |
35 - 60 |
45 - 95 |
20 - 50 |
| z For youngest fully expanded leaves. |
Read the article on Mineral Nutrition of Carnivorous Plants
Pyro Clay
© 2005, M.R. Evans |