Dr. Stanley L. Chapman, Extension Soils Specialist
Questions often arise about
interpretations of soil test results and recommendations. Such interpretations can be particularly confusing
when different labs report test results in different terms.
Soil
tests for plant nutrients are usually reported in parts per million (ppm)
or pounds per acre (lbs/A). Until
the 1980s, two common extractants for soil test phosphorus (P) were the Weak
Bray (P1) and the Strong Bray (P2). The University of Arkansas used the Weak Bray P test until 1987
when they converted to Mehlich III. Ammonium
acetate was formerly used to extract the cations. Mehlich III is more universal extractant for
all of the soil test elements except nitrate-N.
The
University of Arkansas Soil Testing Lab reports all routine elements in pounds
per acre. Soil test results may also
be reported in milli-equivalents per 100 grams (meq/100g). Soil test research results are usually reported
in this manner. A milli-equivalent
is 1/1000 of the gram-equivalent weight of the element. For example, the gram-equivalent weight of
potassium is 39 grams; the milli-equivalent weight is .039 gram.
Parts
per million (ppm) and meq/100g can be readily converted to pounds per acre
as shown below. “Lbs per acre” refers
to the pounds in the upper 6 to 7 inches of surface soil weighing 2,000,000
pounds.
Ways of Expressing Soil Test Results
|
How to Convert to Lbs Per Acre
|
||
|
Parts per million (ppm) |
Multiply by 2 |
|
|
|
Milli-equivalents per 100 grams (meq/100g) |
Multiply the values for: Calcium (Ca) Magnesium (Mg) Potassium (K) Nitrate (N03) Sodium (Na) |
by by by by by |
400 240 780 1240 460 |
Pounds per acre test results
may be converted to ppm or meq/100g by reversing the calculations.
Cation exchange capacity
(CEC) is generally measured as the relative amount of cations (positively
charged ions) displaced by ammonium ions or other known cation. The CEC is roughly equivalent to the sum of
the exchangeable hydrogen, potassium, sodium, magnesium and calcium ions and
may be expressed as “total cations” or CEC in meq/100g.
The
more humus and clay, the higher is the CEC.
The CECs of most Arkansas soils vary from 5 or less in light, low organic
matter sandy soils to over 50 in heavy clay soils.
Percent
saturation is calculated by dividing the CEC or total cations (in meq/100g)
into the meq of the particular cation in question. For example: Assume the
CEC of a particular soil is 15 meq/100g and it contains 3 meq/100g of magnesium.
Divide 15 into 3 and multiply by 100 to get 20 percent magnesium saturation.
Percent saturation with the other cations is similarly calculated. Normally, percent K saturation will be greater
than 1.0; percent Mg saturation will be greater than 5.0; and percent Mg saturation
will be greater than percent K saturation. Percent sodium (Na) saturation is commonly
expressed as exchangeable sodium percentage (ESP). Values greater than 15 percent in the subsoil indicate a sodic soil.
Percent sodium saturation values greater than 10 – percent in the topsoil
should be reason for concern.
The
ideal base saturation concept is based on the principle that availability
of a given cation is influenced by the concentration of other cations present. We do not disagree with this principle. However, we know that plants remove soil nutrients
efficiently over a reasonably wide range – not just at the “ideal” point;
therefore, we rely more on response data that show specific nutrient needs
by similar soils.
The
following is an example of how University of Arkansas soil test results relate
to the milli-equivalent base saturation concept.
|
Cation |
Soil Test Value
Lbs/A |
|
Divide By |
|
Converted to Meq/100g |
Percent Saturation |
|
Calcium Magnesium Potassium Sodium |
1600 120 195 230 |
÷ |
400 240 780 460 |
= |
4.00 0.50 0.25 0.50 5.25 |
55.2 6.9 3.4 6.9 72.4 |
|
Total bases |
||||||
|
Hydrogen |
PH 6.5 |
|
(Est.
from pH) |
|
2.00 |
27.6 |
|
|
|
|
Total
cations (CEC) |
|
7.25 |
100.0 |
In
this example, the percent saturation of the CEC is 55.2 for calcium, 6.9 for
magnesium, 3.4 for potassium, 6.9 for sodium and 72.4 for total base saturation. Hydrogen is the only cation shown that is not
a base; but since it is a positive ion (cation), it participates in this cation
exchange process. Hydrogen is the
main acidic ion.
While
University of Arkansas agronomists consider CEC in a broad sense in making
fertilizer and lime recommendations, some commercial labs and some state labs
use it more specifically and make recommendations for lime and potassium in
higher amounts with increasing CEC. Some
soil scientists believe that the cation exchange capacity should be saturated
by specific percentages of the base cations – Ca, Mg and K. Hence the terms “percent base saturation.”
For example, there is some agreement that for general crop needs, the
soil CEC should be saturated 65 to 85 percent by Ca, 6 to 12 percent by Mg,
and 2 to 5 percent by K. This concept leans more toward “fortifying
the soil” than our philosophy of fertilizing for specific plant needs.
Some
labs request and recommend for desired yield goals. The University of Arkansas considers the soil profile, yield response
data and weather limitations; recommendations aim at the highest economical
yield attainable with good management.
Revised,
January, 1999
The Arkansas
cooperative Extension Service offers its programs to all eligible persons
regardless of race, color, national origin, religion, gender, age, disability,
marital or veteran status, or any other legally protected status, and is an
Equal Opportunity Employer.
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