Please contact the correspondence author for reprints of all published articles
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Mineralogy of the sources for magnetic anomalies on Mars
Gunther Kletetschka*, Peter J. Wasilewski and Patrick T. Taylor
*Correspondence author's address: Mail Code 691, NASA Goddard Space Flight Center, Greenbelt, Maryland 20771, USA; e-mail address: gunther@denali.gsfc.nasa.gov
Abstract–Recent discovery of intense magnetic anomalies on Mars,
which are due to remanent magnetization, requires some explanation for
the possible minerals responsible for the anomaly signature. Thermoremanent
magnetization (TRM) in single domain (SD) and multidomain (MD) sized magnetite,
hematite and pyrrhotite, all potential minerals, are considered.
The intensity of TRM (in 0.05 mT) is in descending order: SD sized magnetite,
SD sized pyrrhotite, MD sized hematite, MD sized pyrrhotite, MD sized magnetite,
SD sized hematite. TRM intensity is <4% of the saturation isothermal
remanence (SIRM) for all but the MD hematite, which may have >50% of the
SIRM. Each of these minerals and estimated concentrations of magnetic
remanence carriers (assumed to be titanomagnetite) in the SNC meteorites,
are used in a thin sheet approximation model to reveal the concentration
of each mineral required for the generation of an observed magnetic anomaly
(1500 nT at 100 km altitude) assuming TRM acquisition in a 0.05 mT
(millitesla) magnetic field.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Petrology and geochemistry of the Elephant Moraine A79002 diogenite: A genomict breccia containing a magnesian harzburgite component
David W. Mittlefehldt
Author's address: Mail Code C23, Lockheed Martin SO, 2400 Nasa Road 1, Houston, Texas 77058, USA; e-mail address: david.w.mittlefehldt1@jsc.nasa.gov
Abstract–The Elephant Moraine A79002 (EETA79002) diogenite is a fragmental breccia with a subtle light-dark structure. It is composed of orthopyroxene, with minor olivine, chromite and ubiquitous, inhomogeneously distributed, ~5–500 µm-sized troilite and metal grains. These latter are present in the matrix, and as inclusions in and as symplectic intergrowths with orthopyroxene and olivine. Trace amounts of silica and diopside are also present. Most orthopyroxene compositions (typical orthopyroxenes) are in the narrow range Wo2.1–2.7En74.1–75.6Fs22.2–23.8 like those of most diogenites. A few magnesian orthopyroxenes are present with compositions of Wo1.7–2.5En77.5–80.2 Fs18.2–20.3. These are among the most magnesian orthopyroxenes known from diogenites. A few ferroan orthopyroxenes have compositions of Wo2.1–2.9En71.7–73.7Fs24.2–25.5. Differences in Al2O3, TiO2 and Cr2O3 between the different orthopyroxene groups are inconsistent with a simple igneous fractionation relationship between them. Olivine compositions are Fo75.0–76.9. The olivines could be in equilibrium with the magnesian orthopyroxenes, but not with the typical or ferroan orthopyroxenes that form the bulk of EETA79002. Metal grains exhibit a range of Ni and Co contents and Ni/Co ratios; their compositions indicate that they are primary igneous metal. Metal and troilite grains are more prevalent in the dark samples.
The trace incompatible lithophile element contents of 16 samples are remarkably uniform. Their Yb concentrations are all within their 2 sigma analytical uncertainties of the mean. The uniformity and low content of LREE in EETA79002 indicate that negligible amounts of a trapped liquid component, or foreign material mixed in the breccia, could be present. The siderophile and chalcophile element data show that the light-dark structure is due to the distribution of metal and troilite grains; dark samples contain higher Ni, Co and Se compared to light samples.
EETA79002 appears to contain material from three or more related plutons,
a magnesian harzburgite, and two orthopyroxenites, and is a genomict breccia.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
S. Ghosh, N. C. Pant, T. K. Rao, C. Rama Mohana, J. B. Ghosh, S. Shome, N. Bhandari*, A. D. Shukla and K. M. Suthar
*Correspondence author's address: Physical Research Laboratory, Navarangpura, Ahmedabad, 380009, India; e-mail address: bhandari@prl.ernet.in
Abstract–A wholly crusted single stone which fell in Vissannapeta,
Andhra Pradesh, India has been identified as a cumulate eucrite based on
its primary texture and mineral composition: anorthite(An92.4–94.6),orthopyroxene(En49.1–51.8
Fs44.2–49.7 Wo1.2–4.0) and clinopyroxene (En38.8–46.8
Fs14.8–33.6Wo19.6–46.4). The stone is pyramidal
in shape and the crust shows rib-like flow features indicating that it
had an oriented passage through the atmosphere towards the terminal stage
of its flight. Conditions of its fall, mineralogical characteristics
and results of measurements of cosmogenic radioactivity (26Al,
22Na and 54Mn) and track density are described.
Compared to Piplia Kalan, another eucrite, which fell about 18 months before
Vissannapeta, the observed activity levels of these nuclides are approximately
75% whereas higher activity of 22Na and 54Mn would
be expected from solar cycle modulation of galactic cosmic rays.
These results, as well as the track density gradient indicate that Vissannapeta
was a small body (equal or less than 120kg) in the interplanetary space
wherein the nuclear cascade due to galactic cosmic rays did not develop
fully. Tracks, surface morphology and crustal features indicate at
least two fragmentation events in the atmosphere.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Crystallization of the basaltic shergottites: Insights from crystal size distribution (CSD) analysis of pyroxenes
Rachel C.F. Lentz* and Harry Y. McSween, Jr.
*Correspondence author's address: Department of Geological Sciences, University of Tennessee, Knoxville, Tennessee 37996-1410, USA; e-mail address: rlentz@utk.edu
Abstract–Quantitative petrographic analysis, using the crystal size distribution (CSD) method, provides a novel approach for examining the crystallization histories of basaltic shergottites. Grain number densities at different sizes are plotted against grain size, and the resulting curve relates to the geologic processes involved with the crystallization of the grain population. Most basaltic shergottites are dominated by pigeonite and augite, and since plagioclase is primarily interstitial, and therefore constrained in its growth by the surrounding pyroxenes, we limited our size measurements to the pyroxene phases.
The groundmasses of EET A79001 lithology A and DaG 476 are fine-grained with cumulus pyroxene and interstitial plagioclase glass. Their simple linear CSD plots record a single stage of pyroxene crystallization under steady state conditions of continuous nucleation and growth. The textures of QUE 94201 and EET A79001 lithology B are quite different from the other shergottites, with intergrown pyroxene and plagioclase. Likewise, their CSD plots are also distinct, with curved trends suggesting a lack of large grains, most likely due to interference between simultaneously growing silicate phases. However, the CSD plot shapes are smooth, also implying a single stage of growth. Shergotty and Zagami, with coarser cumulus textures, display CSD plots that are generally linear over most grain sizes. This implies that conditions of nucleation and growth were dominant during formation of the pyroxene populations. Both plots, however, also display kinks, implying multiple stages of growth.
A similar kink is also visible in a CSD plot of only the Mg-rich cores
of Shergotty pyroxenes, suggesting the feature represents changes in conditions
during core crystallization, rather than an event coincident with the change
in composition to the Fe-rich rims. The plot may be interpreted as
representing two stages of core growth with an intervening short hiatus
of nucleation, with continued crystallization associated with ascent of
the magma. Eruption onto the surface probably triggered the compositional
change to Fe-rich rims. CSD analysis of products from a controlled
crystallization study agree with experimental and petrologic estimates
that cooling rates for Zagami were on the order of a few tenths of a degree
per hour. Growth rates derived from these cooling rates suggest crystallization
of Shergotty and Zagami pyroxenes occurred over a period of a few weeks
to months.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Distant ejecta from the Lockne marine-target impact crater, Sweden
Erik Sturkell, Jens Ormö, Jaak Nõlvak and Åsa Wallin
*Correspondence author's address: Nordic Volcanological Institute, Grensásvegur 50, IS-108 Reykjavík, Iceland; e-mail address: erik@norvol.hi.is
Abstract–The Lockne impact event took place in a Middle-Ordovician (455 Ma) epicontinental sea. The impact resulted in an at least 13.5 km wide, concentric crater in the sea floor. Lockne is one of very few locations where parts of an ejecta layer have been preserved outside the crater structure. The ejecta from the Lockne impact rests on progressively higher stratigraphic levels with increasing distance from the crater, hence forming a slightly inclined discontinuity surface in the pre-impact strata. We report on a ~30 cm thick sandy layer at Hallen, 45 km south of the crater centre. This layer has a fining upward sequence in its lower part, followed by low-angle cross-laminations indicating two opposite current directions. It is rich in quartz grains with planar deformation features, and contains numerous, up to 15 cm large, granite clasts from the crystalline basement at the Lockne impact site. The layer is within a sequence dated to the Baltoniodus gerdae conodont subzone. The dating is corroborated by chitinozoans indicating the latest Kukruse time below and the late Idavere above the impact layer. According to the chitinozoans biostratigraphy, some erosion may have occurred due to deposition of the impact layer. The Hallen outcrop, today 45 km from the centre of the Lockne crater, is at present the most distant accessible occurrence of ejecta from the Lockne impact. It is also the most distant location so far found where the resurge of water towards the crater has affected the bottom sediments.
A greater crater diameter than hitherto assumed, thus representing greater
impact energy, might explain the extent of the ejecta blanket. Fluidisation
of ejecta, to be expected at a marine-target impact, might furthermore
have facilitated the wide distribution of ejecta.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Symplectic exsolution in olivine from the Nakhla martian meteorite
Takashi Mikouchi*, Ikiko Yamada and Masamichi Miyamoto
*Correspondence author's address: Mineralogical Institute, Graduate School of Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan; e-mail address: mikouchi@eps.s.u-tokyo.ac.jp
Abstract–The Nakhla meteorite, commonly accepted to have originated
from Mars, is a cumulus clinopyroxenite with ~10 vol.% of Fe-rich olivine.
Almost all olivine grains in Nakhla contain dark lamellar inclusions (>2–3
µm wide). High-resolution scanning and transmission electron
microscopy revealed that the inclusions are complex intergrowth of augite
and magnetite. Such symplectic intergrowth of augite and magnetite
in olivine was known in some terrestrial rocks, lunar rocks and a few meteorites.
The inclusion in Nakhla olivine is the first symplectite found in a martian
rock. Apparently, the presence of Fe3+ in olivine under
an oxidizing condition on Mars caused symplectic exsolution at high temperature
(>900 ºC) during cooling.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Organosilane occurrence in irghizite samples from the Zhamanshin impact crater, Kazakhstan
Marek Zbik*, Marek Jasieniak and Roger St.C. Smart
*Correspondence author's address: Ian Wark Research Institute, University of South Australia, Levels Campus, Mawson Lakes, South Australia 5095, Australia; e-mail address: marek.zbik@unisa.edu.au
Abstract–The composition of surface deposits on vesicle walls
in irghizites (i.e., impact glasses at site) from the Zhamanshin
meteorite crater were studied using time of flight secondary ion mass spectrometry
(ToF-SIMS). The cavity walls are unique interfaces for condensation
of gases from the superheated, high-silica melt during the impact.
Initially, signals from the cavity wall are dominated by hydrocarbon fragments
whereas the glass fracture face surrounding the cavity gave only signals
corresponding to glass components. After 12h in UHV, signals from
the cavity wall are dominated by peaks corresponding to fragments normally
measured from organo-silanes and organo-siloxanes with the majority of
the hydrocarbon signals markedly reduced. Characteristic hydrocarbon
fragments are now observed on the glass fracture surface next to the cavity
in an annulus around the cavity perimeter. There are also minor signals
in this region from organo-silanes and organo-siloxanes. In contrast,
four tektites (Australites) (i.e., glassy distal ejecta) gave no
organo-silane or organo-siloxane signals after the same preparation and
vacuum evaporation procedure. These species appear to be formed only
at the impact site where higher levels of organic material are likely to
be present in soil and are trapped before evaporation. This appears
to be the first report of naturally occurring silicon-organic compounds.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Primordial noble gases in "Phase Q" in carbonaceous and ordinary chondrites studied by closed system stepped etching
Henner Busemann*, Heinrich Baur and Rainer Wieler
*Correspondence author's address: Physics Institute, University of Bern, Sidlerstr. 5, 3012 Bern, Switzerland; e-mail address: busemann@phim.unibe.ch
Abstract–HF/HCl-resistant residues of the chondrites CM2 Cold
Bokkeveld, CV3 (ox.) Grosnaja, CO3.4 Lancé, CO3.7 Isna, LL3.4 Chainpur
and H3.7 Dimmitt have been measured by closed system stepped etching (CSSE)
in order to better characterise the noble gases in "phase Q", a major carrier
of primordial noble gases. All isotopic ratios in phase Q of the
different meteorites are quite uniform, except for (20Ne/22Ne)Q.
As already suggested by precise earlier measurements (Schelhaas et al.,
1990; Wieler et al., 1991; 1992), (20Ne/22Ne)Q
is the least uniform isotopic ratio of the Q noble gases. The data
cluster around 10.1 for Cold Bokkeveld and Lancé and 10.7 for Chainpur,
Grosnaja and Dimmitt, respectively. No correlation of (20Ne/22Ne)Q
with the classification or the alteration history of the meteorites has
been found. The Ar, Kr and Xe isotopic ratios for all six samples
are identical within their uncertainties and similar to earlier Q determinations
as well as to Ar-Xe in ureilites. Thus, an unknown process probably
accounts for the alteration of the originally incorporated Ne-Q.
The noble gas elemental compositions provide evidence that Q consists of
at least two carbonaceous carrier phases "Q1" and "Q2"
with slightly distinct chemical properties. (Ar/Xe)Q and (Kr/Xe)Q
reflect both thermal metamorphism and aqueous alteration. These parent
body processes have led to larger depletions of Ar and Kr relative to Xe.
In contrast, meteorites that suffered severe aqueous alteration, such as
the CM chondrites, do not show depletions of He and Ne relative to Ar but
rather the highest (He/Ar)Q and (Ne/Ar)Q ratios.
This suggests that Q1 is less susceptible to aqueous alteration
than Q2. Both sub-phases may well have incorporated noble
gases from the same reservoir, as indicated by the nearly constant, though
very large depletion of the lighter noble gases relative to solar abundances.
However, the elemental ratios show that Q1 and Q2
must have acquired (or lost) noble gases in slightly different element
proportions. Cold Bokkeveld suggests that Q1 may be related
to presolar graphite. Q1 and Q2 might be related
to the sub-phases that have been suggested by Gros and Anders (1977). The
distribution of the 20Ne/22Ne ratios can not be attributed
to the carriers Q1 and Q2. The residues of Chainpur
and Cold Bokkeveld contain significant amounts of Ne-E(L), and the data
confirm the suggestion of Huss (1997) that the 22Ne-E(L) content,
and thus the presolar graphite abundances, are correlated with the metamorphic
history of the meteorites.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Light noble gases and cosmogenic radionuclides in Estherville, Budulan, and other mesosiderites: Implications for exposure histories and production rates
A. Albrecht, C. Schnabel, S. Vogt, S. Xue, G. F. Herzog, F. Begemann, H. W. Weber, R. Middleton, D. Fink and J. Klein
Correspondence author's address Department of Chemistry, Rutgers University, New Brunswick, New Jersey 08903, USA; e-mail address: herzog@rutchem.rutgers.edu
Abstract–We report measurements of 26Al, 10Be, 41Ca, and 36Cl in the silicate and metal phases of 11 mesosiderites, including several specimens each of Budulan and Estherville, of the brecciated meteorite Bencubbin, and of the iron meteorite Udei Station. Average production rate ratios (atom/atom) for metal phase samples from Estherville and Budulan are 26Al/10Be = 0.79 ± 0.03; 36Cl/10Be = 5.3 ± 0.2. For a larger set of meteorites that includes iron meteorites and other mesosiderites, we find 26Al/10Be = 0.72 ± 0.01 and 36Cl/10Be = 4.5 ± 0.2. The average 41Ca/36Cl production rate ratio is 1.10 ± 0.04 for metal separates from Estherville and four small iron falls. The 41Ca activities in dpm/(kg Ca) of various silicate separates from Budulan and Estherville span nearly a factor of 4, from <400 to >1600, indicating preatmospheric radii of >30 cm. After allowance for composition, the activities of 26Al and 10Be (dpm/kg silicate) are similar to values measured in most ordinary chondrites and appear to depend only weakly on bulk Fe content. Unless shielding effects are larger than suggested by the 36Cl and 41Ca activities of the metal phases, matrix effects are unimportant for 10Be and minor for 26Al.
Noble gas concentrations and isotopic abundances are reported for samples
of Barea, Emery, Mincy, Morristown, and Marjalahti. New estimates
of 36Cl/36Ar exposure ages for the metal phases agree
well with published values. Neon-21 production rates for mesosiderite
silicates calculated from these ages and from measured 21Ne
contents are consistently higher than predicted for L chondrites despite
the fact that the mesosiderite silicates have lower Mg contents than L
chondrites. We suggest that the elevation of the 21Ne
production rate in mesosiderite silicates reflects a "matrix effect," that
is, the influence of the higher Fe content of mesosiderites, which acts
to enhance the flux of low-energy secondary particles and hence the 21Ne
production from Mg. As 10Be production is relatively insensitive
to this matrix effect, 10Be/21Ne ages give erroneously
low production rates and high exposure ages. By coincidence, standard
22Ne/21Ne based "shielding" corrections give fairly
reliable 21Ne production rates in the mesosiderite silicates.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
A nitrogen isotope study of bencubbinites
N. Sugiura*, S. Zashu, M. Weisberg and M. Prinz
*Correspondence author's address: Department of Earth and Planetary Science, Univ. of Tokyo, Tokyo, Japan; e-mail address: sugiura@eps.s.u-tokyo.ac.jp
Abstract–Nitrogen isotopic compositions in the bencubbinites
(Bencubbin, Hammadah al Hamra 237 (HH 237) and Queen Alexandra Land 94411
(QUE 94411)) and in a petrographically similar chondrite Grosvenor Mountains
95551 (GRO 95551) were measured by stepped combustion-static
mass spectrometry. HH 237 and QUE 94411 contain isotopically heavy
N, but not as heavy as that in Bencubbin or Weatherford. GRO 95551
contains isotopically near-normal N and light N and hence it is not related
to the bencubbinites, as also indicated by its oxygen isotope composition.
The N carriers in these meteorites were investigated using secondary
ion mass spectrometry (SIMS). In the bencubbinites, N is mostly located
around sulfide in metal clasts and in impact melt areas. The N carriers
in the former are taenite and/or carbide, whereas those in the latter are
molten metal, tiny graphitic carbon in metal and/or oxi-nitride glass.
N in the various N carriers is isotopically equilibrated, and therefore
the carriers are not pristine presolar grains. Isotopically near-normal
N in GRO 95551 is located in graphite. The carrier of isotopically
light N in GRO 95551 has not been found.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Isotopic compositions of different presolar SiC size fractions from the Murchison meteorite
Sachiko Amari*, Ernst Zinner and Roy S. Lewis
*Correspondence author's address: Laboratory for Space Sciences and the Physics Department, Washington University, One Brookings Drive, St. Louis, Missouri 63130-4899, USA; e-mail address: sa@howdy.wustl.edu
Abstract–We report measurements of isotopic ratios of C, N, Mg,
Si, Ca, Ti, Cr and Fe in bulk samples (aggregates of many grains) of up
to seven different fractions of SiC, ranging from 0.38 to 3.0 µm
in diameter, from the Murchison CM2 carbonaceous chondrite. 12C/13C
ratios range from 37 to 42 and 14N/15N ratios from
370 to 520, within the range of single grain measurements on coarser samples
and in agreement with an asymptotic giant branch (AGB) star origin of most
of the grains. Variations among size fractions do not show any simple
trend and can be explained by varying contamination with isotopically normal
material. Silicon isotopic ratios vary only little and, with one
exception, lie to the right of the single-grain mainstream correlation
line. This might indicate a higher percentage of the minor populations
Y and Z among finer grain size fractions. All bulk samples have large
26Mg excesses attributed to the presence of short-lived 26Al
at the time of grain formation. Inferred 26Al/27Al
ratios are much larger than those measured in single larger mainstream
grains. This is probably because of the presence of SiC grains of
type X; we obtain an estimate of 0.4 for their 26Al/27Al
ratio. Our Ca isotopic measurements, the first made on presolar SiC
grains, show excesses in 42Ca and 43Ca, in general
agreement with theoretical expectations for AGB stars. 44Ca
excesses are much larger than expected and are probably due to X grains,
which have high 44Ca excesses due to the decay of short-lived
44Ti produced in supernova explosions. We arrive at an
estimate of 0.014 for the initial 44Ti/48Ti ratio
of the X grains, within the range obtained from previous single X grain
measurements. The Ti isotopic ratios of the bulk samples show a V-shaped
pattern with excesses of all isotopes relative to 48Ti.
46Ti, 47Ti and 50Ti show excesses relative
to the correlation between Ti and Si ratios for single grains and are in
general agreement with theoretical models of s-process nucleosynthesis
in AGB stars. In contrast, 49Ti does not show any excess
relative to the single grain data; it also fails to agree with theory,
which predicts much larger excesses than observed. Measured 53Cr/52Cr
and 57Fe/56Fe ratios are normal within errors.
The first result is expected even for Cr in AGB star envelopes, but the
second result suggests that most of the Fe analyzed originates from contamination.
We have found no simple trends in isotopic composition with respect to
grain size that can be interpreted in terms of nucleosynthetic origin,
unlike the results for Kr, Xe, Ba, and Sr.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
On the origin of rim textures surrounding anhydrous silicate grains in CM carbonaceous chondrites
Lauren Browning*, Harry Y. McSween, Jr. and Michael E. Zolensky
*Correspondence author's address: Center for Nuclear Waste Regulatory
Analyses, Southwest Research Institute, San Antonio, Texas 78238-5166,
USA; e-mail address: lbrowning@swri.edu
Abstract–Fine-grained, optically opaque rims coating individual
olivine and pyroxene grains in CM matrices and chondrules. Bulk chemical
analyses and observations of these rims indicate the presence of phyllosilicates
and disseminated opaques. Because phyllosilicates could not have
survived the chondrule formation process, chondrule silicate rims must
have formed entirely by late-state aqueous reactions. As such, these
textures provide a useful benchmark for isolating alteration features from
more complex CM matrix materials. Both chondrule silicate and matrix
silicate rims exhibit morphological features commonly associated with advancing
stages of replacement reactions in terrestrial serpentinites. Contacts
between many matrix silicate rims and the adjacent matrix materials suggest
that these rims formed entirely by aqueous reactions in a parent body setting.
This contrasts with previous assertions that rim textures can only form
by the accretion of nebular dust, but does not imply an origin for the
rims surrounding other types of CM core components, such as chondrules.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Interrelationships among meteoric metals, meteors, interplanetary dust, micrometeorites, and meteorites
Frans J. M. Rietmeijer
Author's address: Institute of Meteoritics, Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico 87131, USA; e-mail address: fransjmr@unm.edu
Abstract–Meteor science, Aeronomy and Meteoritics are different
disciplines with natural interfaces. This paper is an effort to integrate
the chemistry and mineralogy of collected interplanetary dust particles
(IDPs), micrometeorites and meteorites with meteoric data and with atmospheric
metal abundances. Evaporation, ablation and melting of decelerating materials
in the Earth's atmosphere are the sources of the observed metal abundances
in the upper atmosphere. Many variables ultimately produce the materials
and phenomena we can analyze, such as different accretion and parent body
histories of incoming extraterrestrial materials, different interactions
of meteors with the Earth's middle atmosphere, meteor data reduction and
complex chemical interactions of the metals and ions with the ambient atmosphere.
IDP-like and UOC matrix materials are reasonable sources for observed meteoric
and atmospheric metals. The hypothesis of hierarchical dust accretion predicts
that low, correlated refractory element abundances in cometary meteors
may be real. It implies that the CI or cosmic standard is not useful to
appreciate the chemistry of incoming petrologically heterogeneous cometary
matter. The quasi steady state metal abundances in the lower thermosphere
and upper mesosphere are derived predominantly from materials with cometary
orbital characteristics and velocities such as comets proper and near-earth
asteroids. The exact influence of atmospheric chemistry on these abundances
still needs further evaluation. Metal abundances in the lower mesosphere
and upper stratosphere region are mostly from materials from the asteroidal
belt and the Kuiper belt.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Evidence for common break-up events of the acapulcoites/lodranites and chondrites
Dario Terribilini, Otto Eugster*, Gregory F. Herzog and Christoph Schnabel
*Correspondence author's address: Physikalisches Institut, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland; e-mail address: eugster@phim.unibe.ch
Abstract–Acapulcoites and lodranites are believed to originate
on a common parent body and to represent some of the earliest events in
the differentiation of the chondritic asteroids. We have conducted
isotopic studies of the noble gases He, Ne, Ar, Kr, and Xe and determinations
of the concentrations of the major elements and of the radionuclides 10Be,
26Al, and 36Cl in an attempt to constrain the cosmic-ray
exposure history of two members of the acapulcoite / lodranite clan recovered
in Antarctica: Frontier Mountain 95029 and Graves Nunataks 95209.
From cosmic-ray produced 3He, 21Ne, and 38Ar
and appropriate production rates we derive parent body break-up times of
4.59 ± 0.60 Ma and 6.82 ± 0.60 Ma for FRO95209 and GRA95209,
respectively. These times are consistent with those obtained from
the pairs 10Be-21Ne and 26Al-21Ne,
whereas the times inferred from the pair 36Cl-36Ar
are slightly longer, perhaps because the 36Cl activities decreased
as a result of decay on Earth. Terrestrial ages up to ~50 ka for
the two meteorites are consistent with the measured 36Cl activities
of the metal phases. All acapulcoites and lodranites dated until
now show cosmic-ray exposure ages in the range of 4–10 Ma. This is
the same range as that found for the major exposure age cluster of the
H chondrites. As a common parent body is improbable on the basis
of the oxygen isotope systematics, a common set of impactors might have
affected the asteroid belt 4–10 Ma ago.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Refractory inclusions from the ungrouped carbonaceous chondrites MAC 87300 and MAC 88107
Sara S. Russell, Andrew M. Davis, Glenn J. MacPherson*, Yunbin Guan and Gary R. Huss
*Correspondence author's address: Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution, Washington, D.C. 20560-0119, USA; e-mail address: glenn@glennm.si.edu
Abstract–MAC 87300 and MAC 88107 are two unusual carbonaceous
chondrites that are intermediate in chemical composition between the CO3
and CM2 meteorite groups. Calcium-aluminum-rich inclusions (CAIs)
from these two meteorites are mostly spinel-pyroxene and melilite-rich
(Type A) varieties. Spinel-pyroxene inclusions have either a banded
or nodular texture, with aluminous diopside rimming iron-poor spinel.
Melilite-rich inclusions (Åk4–42) are irregular in shape
and contain minor spinel (FeO <1 wt%), perovskite and, more rarely,
hibonite. The CAIs in MAC 88107 and MAC 87300 are similar in primary
mineralogy to CAIs from low petrologic grade CO3 meteorites, but differ
in that they commonly contain phyllosilicates. The two meteorites
also differ somewhat from each other: melilite is more abundant and slightly
more aluminum-rich in inclusions from MAC 88107 than in those from MAC
87300, and phyllosilicate is more abundant and magnesium-poor in MAC 87300
CAIs relative to that in MAC 88107. These differences suggest that
the two meteorites are not paired. CAI sizes and the abundance of
melilite-rich CAIs in MAC 88107 and MAC 87300 suggests a genetic relationship
to CO3 meteorites, but the CAIs in both have suffered a greater degree
of aqueous alteration than is observed in COs. Al-rich melilite
in CAIs from both meteorites generally contains excess 26Mg,
presumably from the in situ decay of 26Al. Although
well-defined isochrons are not observed, the 26Mg excesses are
consistent with initial 26Al/27Al ~3–5 × 10–5.
An unusual hibonite-bearing inclusion is isotopically heterogeneous, with
two large and abutting hibonite crystals showing significant differences
in their degrees of mass-dependent fractionation of 25Mg/24Mg.
The two crystals also show differences in their inferred initial 26Al/27Al,
1 × 10-5 vs. 3 × 10-6.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
The age of the Kaalijärv meteorite craters
Kaare L. Rasmussen*, Bent Aaby and Raymond Gwozdz
*Correspondence author's address: Radiocarbon Laboratory, National Museum of Denmark, Ny Vestergade 11, DK-1471 Copenhagen K, Denmark; e-mail address: kaare.lund.rasmussen@natmus.dk
Abstract–Precise radiometric age determination of the Kaalijärv
meteorite craters on the island of Saaremaa in Estonia have so far proved
inconclusive. Here we present trace element analyses of peat cores
taken several kilometers away from the Kaalijärv craters that reveal
a distinct Ir-enriched layer produced by the meteorite impact. By
radiocarbon dating the peat cores we have determined for the first time
the precise age of the impact that generated the Kaalijärv craters.
The calibrated date of the impact is 400–370 BC at ± one standard
deviation.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Complexities on the acapulcoite-lodranite parent body: Evidence from trace element distributions in silicate minerals
Christine Floss
Author's address: Laboratory for Space Sciences and the Department of Earth and Planetary Sciences, Washington University, St. Louis, Missouri 63130, USA; e-mail address: floss@howdy.wustl.edu
Abstract–The trace element distributions of individual minerals from seven acapulcoites and lodranites have been studied. Systematic differences are evident between some members of the two groups. Specifically, pyroxenes from the lodranites MAC 88177 and LEW 88280 exhibit depletions of the REE and other incompatible trace elements (Ti, Zr, Y), relative to acapulcoite (Acapulco, ALHA81261) pyroxenes, that are consistent with the formation and removal of 15 % or more silicate partial melts from these meteorites. Phosphate REE patterns in these lodranites also support this scenario. However, other members of the acapulcoite-lodranite clan exhibit more complex trace element variations. EET 84302, which has been classified as transitional between the acapulcoites and lodranites generally has trace element characteristics similar to the acapulcoites. However, its plagioclase REE compositions suggest a somewhat greater degree of metamorphism than that experienced by acapulcoites such as Acapulco and ALHA81261. Similar and elevated REE abundances in the silicate phases from acapulcoite ALHA81187 and lodranite GRA 95209 suggest that these two meteorites, in fact, experienced similar thermal histories. This probably included some silicate partial melting, although little melt appears to have been lost from the samples.
The observed variations in the trace element abundances of these samples
from the acapulcoite-lodranite clan emphasize the complex and varied processes
that have acted on their parent body. The simple bimodal classification
of these meteorites based primarily on petrographic criteria, which has
been used to date, appears to be inadequate to describe this diverse group
of samples, as they represent a range of degrees of partial melting, both
with and without accompanying melt migration. In some instances,
secondary processes on the parent body, such as cryptic metasomatism, have
further modified sample compositions.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
The differentiation of eucrites: The role of in situ crystallization
J. A. Barrat*, J. Blichert-Toft, Ph. Gillet and F. Keller
*Correspondence author's address: Université d'Angers, Faculté des Sciences, 2 Bd Lavoisier, 49045 Angers Cedex, France; e-mail address: barrat@univ-angers.fr
Abstract–We report on major and trace element analyses of 17 eucrites, including three cumulate eucrites (Binda, Moore County, and Serra de Magé), determined by, respectively, ICP-AES and ICP-MS. The results obtained for Binda and Moore County are consistent with the model of Treiman (1997) for the formation of cumulate eucrites, which holds that these meteorites were produced from a eucritic melt. Our sample of Serra de Magé contains unusually large amounts of pyroxene and probably an accessory phase rich in HREEs and is therefore not representative of this eucrite as known from literature data.
Our results for the noncumulate eucrites Bereba, Bouvante, Cachari,
Caldera, Camel Donga, Ibitira, Jonzac, Juvinas, Lakangaon, Millbillillie,
Padvarninkai, Pasamonte, Sioux County and Stannern are in good agreement
with literature data. The observed decoupling between major and trace
elements for noncumulate eucrites can be explained by in-situ crystallization
during the differentiation of an asteroidal magma ocean. This model
can further account for both the Nuevo Laredo and the Stannern trends but
has as a consequence that none of the analyzed eucrites represents a primary
melt.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
Space weathering on airless bodies: Resolving a mystery with lunar samples
Carlé M. Pieters*, Larry A. Taylor, Sarah K. Noble, Lindsay P. Keller, Bruce Hapke, Richard V. Morris, Carl C. Allen, David S. McKay and Susan Wentworth
*Correspondence author's address: Department of Geological Sciences, Brown University, Providence, Rhode Island 02912, USA; e-mail address: pieters@mare.geo.brown.edu
Abstract–Using new techniques to examine the products of space
weathering of lunar soils, we demonstrate that nanophase reduced iron (npFe0)
is produced on the surface of grains by a combination of vapor deposition
and irradiation effects. The optical properties of soils (both measured
and modeled) are shown to be highly dependent on the cumulative amount
of npFe0, which varies with different starting materials and
the energetics of different parts of the solar system. The measured
properties of intermediate albedo asteroids, the abundant S-type in particular,
are shown to directly mimic the effects predicted for small amounts of
npFe0 on grains of an ordinary chondrite regolith. This
measurement and characterization of space weathering products seems to
remove a final obstacle hindering a link between the abundant ordinary
chondrite meteorites and common asteroids.
Meteoritics & Planetary Science 35 (2000)
© Meteoritical Society, 2000. Printed in USA.
New type of radiation of bright Leonid meteors above 130 km
Pavel Spurný* , Hans Betlem, Klaas Jobse, Pavel Koten and Jaap Van't Leven
*Correspondence author's address: Astronomical Institute, Ondrejov Observatory, 251 65 Ondrejov, Czech Republic; e-mail address: spurny@asu.cas.cz
Abstract–In this paper we study the extremely high beginning parts of atmospheric trajectories of seven Leonid meteors recorded by sensitive TV systems equipped with image intensifiers up to apparent magnitude +6.5. For all the seven cases we observed comet-like diffuse structures with sizes of the order of kilometers and quickly developing during the meteoroid penetration through the atmosphere. For the brightest event with maximum absolute magnitude of -12.5, we observed an arc looking like a solar protuberance and producing a jet detectable several kilometers sideways from the brightest parts of the meteor head, and moving with velocities over 100 km/s. These jets are common features for the seven studied meteors. Precise position in trajectory, velocity and brightness at each point is available for all seven meteors, because of double-station records on 85 km base-line. When these meteoroids reached 130 km height, this diffuse structure of the radiation quickly transformed to usual meteor appearance resembling moving droplet, and a meteor train started to develop. These meteor phenomena above 130 km were not recognized before our observations, and they cannot be explained by standard ablation theory.
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